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발표분야
분자전자 부문위원회
발표 구분
포스터발표
제목
Facet–Growth Correlation Bypass Enables Dimensional Tuning in Blue-Emissive Perovskite Quantum Dots
발표자

김희은 (국민대학교)

연구책임자

김영훈 (국민대학교)

초록

내용
Perovskite quantum dot (PQD) synthesis often relies on anisotropic growth directed by oleylammonium (OLAM⁺) ions that selectively bind to specific crystal facets. This facet-specific interaction induces a strong correlation between surface chemistry and growth direction, limiting shape control. Lattice incorporation of OLAM⁺ further reinforces this correlation, restricting morphological freedom. We present a nucleophilic strategy that enables early halide release via SN2 reaction at lower activation energy than oleylamine, promoting isotropic nucleation before OLAM⁺-driven anisotropy. This temporal separation between nucleation and passivation relaxes facet-dependent growth, enabling dimensional control. OLAM⁺ then acts as a passive stabilizer, maintaining colloidal integrity without directing shape. This approach provides a general route to morphology-controlled PQDs and achieves stable blue emission through shape-regulated quantum dot formation.
발표코드
1PS-159
발표일정
2025-09-30 09:00 - 10:30